Melt Flow Rate (MFR, MVR)

The Melt Flow Rate is a measure of the ease of flow of melted plastic and represents a typical index for Quality Control of thermoplastics. Originally called Melt Flow Index or Melt Index (typically for polyethylene, but applied to a variety of materials), the standard designation today is Melt Mass-Flow Rate or MFR, which is a mass flow expressed (SI units) in g/10min. An alternative quantity is the volume flow expressed (SI units) in cm3/10min, called Melt Volume-Flow Rate or MVR. MVR multiplied by the melt density (i.e. density of the material in the melted state) gives MFR.

Typical Melt Flow instruments are compact and easy to use. The basic principle is that a thermoplastic sample (originally in the shape of granules, powder or flakes) is made fluid by heating and forced to flow out of a cylinder through a capillary die. The extruding piston is loaded with dead weights, normally up to 21.6 kg. MFR (and MVR) are obtained under standard conditions of temperature and applied load, defined for each type of material, and normally using a fixed type of die (inner diameter 2.095 mm, length 8 mm). The result must always specify the test conditions because it’s strongly dependent on those.

MFR and MVR are typically used in Quality Control labs and Production Control labs. The basic procedure foresees a manual timing, cutting and weighing of the extruded material, giving directly a value of MFR. Semi-automatic procedures allowed by modern instruments are based on direct measurements of piston displacement, hence they give directly a value of MVR. Melt density can be typed in or measured, and therefore MFR results are also obtained. Semi-automatic procedures can achieve a much higher accuracy and guarantee a wider range of measurable flow rates. More advanced methods foresee the application of several loads during the same test, each one giving a MFR (MVR) result. This is called a multiweight test and gives additional information on the sample, with some insight on the shear dependence of viscosity. A single-weight MFR test can be correlated with average molecular mass, while the shear dependence depends on the molecular mass distribution.

Melt flow rate is a quick tool to compare batches of the same material or to estimate flow properties of different materials (typically for extrusion processes), when a deep understanding of material properties is not required. A true rheological characterization can be carried out by means of rheometers. Melt flow rate is inversely proportional to (shear) viscosity, but is not used to determine the latter (can give just a rough estimation).

References

  • ISO 1133:2005 "Plastics - Determination of the Melt Mass-Flow Rate (MFR) and Melt Volume-Flow Rate (MVR) of Thermoplastics”
  • ASTM D1238-10 "Standard Test Method for Melt Flow Rates of Thermoplastics by Extrusion Plastometer“